Process for separating linear internal olefins from branched...

C - Chemistry – Metallurgy – 07 – C

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C07C 11/02 (2006.01) C07C 7/152 (2006.01)

Patent

CA 2313327

A process for separating linear internal olefins from branched internal olefins. There is provided a process for converting a feedstock of linear internal olefins and branched internal olefins to a primarily linear internal olefin composition having a lower concentration of branched internal olefins than present in the feedstock, by: a) contacting the feedstock with a linear polyaromatic, optionally substituted, compound under conditions effective to form a linear polyaromatic compound-linear internal olefin adduct; b) separating the linear polyaromatic compound-linear internal olefin adduct from the reaction mixture; c) dissociating the linear polyaromatic compound-linear internal olefin adduct to form linear polyaromatic compound and a linear internal olefin composition; and optionally d) separating the linear polyaromatic compound formed in step c) from a linear internal olefin composition.

L'invention concerne un procédé qui permet de séparer les oléfines internes linéaires des oléfines internes ramifiées, et plus particulièrement un procédé qui permet de convertir une charge d'alimentation, constituée d'oléfines internes linéaires et d'oléfines internes ramifiées, en une composition d'oléfines internes principalement linéaires ayant une concentration en oléfines internes ramifiées inférieure à celle de la charge. Le procédé comprend les étapes suivantes: a) on met en contact la charge d'alimentation avec un composé polyaromatique linéaire éventuellement substitué, dans des conditions permettant de former un produit d'addition composé polyaromatique linéaire/oléfine interne linéaire; b) on sépare le produit d'addition du mélange de réaction; c) on dissocie le produit d'addition de façon à former un composé polyaromatique linéaire et une composition d'oléfines internes linéaires; et éventuellement d) on sépare le composé polyaromatique linéaire formé à l'étape c) de la composition d'oléfines internes linéaires.

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