Production of allyl chloride

Details Production of allyl chloride Production of allyl chloride

C - Chemistry, Metallurgy

07

C

260/660.2

C07C 17/156 (2006.01) C07C 17/10 (2006.01) C07C 17/158 (2006.01) C07C 17/23 (2006.01) C07C 21/067 (2006.01)

Patent

CA 2004312

A process is provided for the production of allyl chloride from three carbon atom hydrocarbons (propane and/or propylene) using hydrogen chloride or hydrogen chloride/chlorine mixtures as the chlorinating agent. The process includes reaction steps operated in tandem in separate zones first comprising the reaction of perchloroethylene with hydrogen chloride and oxygen in the presence of an oxychlorination catalyst to give hexachloroethane and water, second comprising the vapor phase reaction of hexachloroethane with propane/propylene feedstock to produce allyl chloride, perchloroethylene, and hydrogen chloride, and third isolating the products of the second step and repeating the first step using as starting materials the thus isolated perchloroethylene and hydrogen chloride.

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