Process for preparing thermoplastic hydrogen-containing...

C - Chemistry – Metallurgy – 08 – F

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C08F 214/18 (2006.01) C08F 2/24 (2006.01) C08F 2/38 (2006.01) C08F 14/18 (2006.01) C08F 210/00 (2006.01)

Patent

CA 2144892

Cyclopentanes alkyl-substitued with one or more C1-C6 alkyls are used as chain transfer agents in (co)polymerization reactions carried out, either in suspension or in aqueous emulsion, at low temperatures, comprised between -30° and +30°C, for preparing thermoplastic hydrogen-containing fluoropolymers, such as for instance ethylene/chlorotrifluoroethylene and ethylene/tetrafluoro- ethylene copolymers, or homopolymers and copolymers of vinylidenefluoride. They are transfer agents having high efficiency, which are liquid and thus can be easily handled and dosed, non-toxic, yielding alkyl end groups of high thermal stability.

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