Process for the isomerisation of a hydrocarbonaceous feedstock

C - Chemistry – Metallurgy – 07 – C

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C07C 11/02 (2006.01) B01J 29/84 (2006.01) C07C 5/27 (2006.01)

Patent

CA 2123631

Process for the preparation of branched olefins comprising contacting a hydrocarbonaceous feedstock comprising linear olefins having at least four carbon atoms at elevated temperature with a catalyst which comprises a MeAPO and/or MeAPSO medium-pore molecular sieve having an anhydrous composition expressed in molar oxide ratios as follows (MeO)a(A12O3)b(P2O5)c(SiO2)d, whereby (a + b)/c is greater than 1.0, a ranges from 0.003 to 0.2, b and c range from 0.05 to 0.3, d is at most 0.4 and a/(c + d) is at least 0.05 when SiO2 is present, and Me is at least one of Mg, Mn, Co and Zn.

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