One-step synthesis of methyl t-butyl ether from t-butanol...

C - Chemistry – Metallurgy – 07 – C

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C07C 43/04 (2006.01) C07C 41/01 (2006.01) C07C 41/09 (2006.01)

Patent

CA 2139989

Disclosed is a method for producing alkyl tertiary alkyl ethers which comprises reacting t-butanol with an alkanol in the presence of a catalyst which exhibits extended life comprising .beta.-zeolite modified with one or more metals selected from the group consisting of Group IA and Group IIIB of the Periodic Table and continuously contacting said alkanol and t-butanol in a molar amount from about 10:1 to 1:10 over said zeolite catalyst at a temperature of about 20°C to about 250°C and a pressure of about atmospheric to about 1000 psig.

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