Process for polyolefin production using fluorinated...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/02 (2006.01) C08F 4/6592 (2006.01) C08F 10/00 (2006.01)

Patent

CA 2644689

Catalyst systems, polymers and methods of forming the same are described herein. The catalyst systems generally include an inorganic support material having a bonding sequence selected from Si-O-Al-F, F-Si-O-Al, F-Si-O-Al-F and combinations thereof, wherein the inorganic support material has an acid strength (pKa) of less than about 4.8 and a transition metal compound, wherein the transition metal compound is represented by the formula [L]mM[A]n; wherein L is a bulky ligand, A is a leaving group, M is a transition metal and m and n are such that a total ligand valency corresponds to a transition metal valency.

L'invention concerne des systèmes de catalyseurs, des polymères et des procédés de formation de ceux-ci. Les systèmes de catalyseurs comprennent de manière générale une matière support inorganique qui présente une séquence de liaison sélectionnée dans le groupe comprenant Si-O-Al-F, F-Si-O-Al, F-Si-O-Al-F et des combinaisons de ceux-ci, cette matière présentant une force d'acide (pKa) inférieure à environ 4,8; et un composé de métal de transition, représenté par la formule [L]mM[A]n, dans laquelle L représente un ligand volumineux, A représente un groupe partant, M représente un métal de transition et m et n sont tels que la valence totale du ligand correspond à la valence du métal de transition.

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