Process for preparing polyolefins

Details Process for preparing polyolefins Process for preparing polyolefins

C - Chemistry, Metallurgy

08

F

C08F 2/34 (2006.01) C08F 10/00 (2006.01)

Patent

CA 2116047

ABSTRACT According to the present invention, in a vapor phase polymerization of olefins, there is provided an efficient polyolefin manufacturing process capable of preventing the formation of a sheet-like polymer and allowing an olefin polymerization reaction to be started stably. More particularly, there is provided a process of preparing a polyolefin by homopolymerizing or copolymerizing an olefin or olefins substantially in a vapor phase condition and in the presence of a catalyst comprising a solid catalyst component and an organometallic compound, the solid catalyst component containing magnesium, one or more elements selected from titanium and vanadium and also containing halogen, wherein, in feeding the catalyst into a reactor the interior of which is held substantially in a vapor phase condition, in the presence of a polyolefin serving as a medium for dispersing the catalyst and in a state not substantially inducing a polymerization reaction in the presence of only the said polyolefin serving as the said medium, to start homopolymerization or copolymerization of the olefin(s), a solid catalyst component satisfying the above condition and having an average particle diameter substantially larger than that of the solid catalyst component to be used in a principal stage of the polymerization reaction is used at least until an olefin - 1 - homopolymer or copolymer is formed in an amount equal to the amount of the polyolefin used as the catalyst dispersing medium. - 2 -

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