One step synthesis of methyl t-butyl ether from t-butanol...

C - Chemistry – Metallurgy – 07 – C

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C07C 41/06 (2006.01) C07C 41/09 (2006.01) C07C 43/04 (2006.01)

Patent

CA 2048017

ONE STEP SYNTHESIS OF METHYL t-BUTYL ETHER FROM t-BUTANOL PLUS METHANOL USING GROUP IV OXIDES TREATED WITH SULFATES OR SULFURIC ACID (D#81,022 - F) ABSTRACT OF THE DISCLOSURE Disclosed is a method wherein t-butanol is reacted with methanol in one step to provide methyl t-butyl ether at a temperature of about 20°C to 250°C and a pressure of about atmospheric to about 1000 psig employing a catalyst consisting of a Group IV oxide on which there has been deposited a sulfur-containing compound from the group consisting of ammonium sulfate or sulfuric acid. CLK:pg CK\81022.APP

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