Modified aminoplast crosslinkers and power coating...

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 12/40 (2006.01) C08G 12/20 (2006.01) C08J 3/24 (2006.01) C09D 5/03 (2006.01) C09D 7/12 (2006.01) C09D 161/32 (2006.01)

Patent

CA 2455780

A crosslinking agent is provided, prepared by reacting (A) an aminoplast resin; (B) a reactive urethane group-containing adduct of a polyfunctional polymer and monoisocyanate, and (C) at least one other compound having active hydrogen groups reactive with aminoplast resin (A). Compound (C) is selected from: (i) compounds having the structure (I): wherein X is aromatic; R1, R2, and R3 each independently represents H, (cyclo)alkyl having from 1 to 12 carbon atoms, aryl, alkaryl, aralkyl, or an active hydrogen-containing group, (ii) compounds having the structure (II) or (III): where R' and R" each independently represents an aromatic group or an alkyl group having 1 to 12 carbon atoms; and (iii) compounds different from (i) and (ii), having a melting point of at least 80~C. Further provided are methods for preparing the crosslinking agent, curable compositions containing the crosslinking agent, and coated substrates.

L'invention concerne un agent de réticulation préparé par mise en réaction (A) d'une résine aminoplaste, (B) d'un produit d'addition contenant un groupe uréthane réactif d'un polymère polyfonctionnel et d'un monoisocyanate et (C) au moins un autre composé possédant des groupes d'hydrogène actifs réactifs avec la résine aminoplaste (A). Le composé (C) est choisi dans le groupe comprenant: (i) des composés possédant la structure (I) dans laquelle X représente un aromatique, R?1¿, R?2¿, et R?3¿ représentent chacun indépendamment H, (cyclo)alkyle possédant de 1 à 12 atomes de carbone, aryle, alkaryle, aralkyle, ou un groupe contenant de l'hydrogène actif, (ii) des composés possédant la structure (II) ou (III) dans lesquelles R' et R" représentent chacun indépendamment un groupe aromatique ou un groupe alkyle possédant de 1 à 12 atomes de carbone, et (iii) des composés différents de (i) et (ii), possédant un point de fusion égal ou supérieur à 80 ·C. L'invention concerne également des procédés de préparation de cet agent de réticulation, des compositions durcissables contenant cet agent de réticulation, et des substrats revêtus.

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