Removal of permanganate reducing compounds from methanol...

C - Chemistry – Metallurgy – 07 – C

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C07C 51/48 (2006.01) C07C 53/08 (2006.01)

Patent

CA 2556899

An improvement of the methanol carbonylation process for manufacturing acetic acid is disclosed. Specifically disclosed is a method for removing permanganate reducing compounds ("PRC's") from the condensed light ends overhead stream, including (a) distilling at least a portion of the condensed light ends overhead to yield a PRC enriched second overhead stream; (b) extracting the second overhead stream with water and separating therefrom an aqueous stream containing PRC's; and (c) returning at least a portion of the extracted second overhead to the second distiller.

L'invention concerne l'amélioration du procédé de carbonylation de méthanol destiné à la production d'acide acétique. L'invention concerne notamment un procédé d'enlèvement de composés réducteurs du permanganate ("PRC's") du flux de tête de fractions légères condensé, ce procédé consistant (a) à distiller au moins une partie du produit de tête de fractions légères condensé pour obtenir un deuxième flux de tête enrichi en PRC; (b) à extraire le deuxième flux de tête avec de l'eau et à en séparer un flux aqueux contenant des composés PRC; et (c) à renvoyer au moins une partie du deuxième produit de tête extrait au deuxième distillateur.

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