Route to glycals in the allal and gulal series

C - Chemistry – Metallurgy – 07 – H

Patent

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C07H 13/06 (2006.01) C07D 309/10 (2006.01) C07D 309/30 (2006.01) C07H 5/10 (2006.01) C07H 15/14 (2006.01) C07H 15/203 (2006.01) C07H 17/00 (2006.01) C07H 23/00 (2006.01)

Patent

CA 2037754

Abstract Axial anomeric sulfoxides generated via thiophenol Ferrier rearrangement of glucal and galactal derivatives are used to synthesize glycals of the gulal and allal series. An application of the method led to the synthesis of the esperamicin thiosugar.

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