Synthesis of macrocyclic polymers having low hysteresis...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/50 (2006.01) C08F 2/38 (2006.01) C08F 4/44 (2006.01) C08F 8/00 (2006.01) C08F 36/04 (2006.01) C08F 136/06 (2006.01) C08F 236/10 (2006.01) C08L 9/06 (2006.01) C08L 25/10 (2006.01)

Patent

CA 2219715

The present invention provides a method of anionic synthesis of stable macrocyclic polymers that are compounded to form vulcanizable elastomeric compounds exhibiting reduced hysteresis properties. Cyclic organometallic compounds containing divalent metal atoms of Groups IIA and IIB of the Periodic System are employed as initiators of anionic polymerization of conjugated diene, vinyl aromatic and/or triene monomers. Coupling of the living ends of the resulting macrocyclic polymers or copolymers with a coupling agent or a coupling agent that is also a functionalizing agent results in stable macrocyclic polymers with improved hysteresis properties.

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