Silyl derivatives of eugenol

Details Silyl derivatives of eugenol Silyl derivatives of eugenol

C - Chemistry, Metallurgy

07

F

C07F 7/08 (2006.01) C07F 7/18 (2006.01) C08F 30/08 (2006.01) C08F 210/00 (2006.01) C08F 230/08 (2006.01)

Patent

CA 2067179

Silyl derivatives of eugenol include compositions of formula (I) where R1, R2 and R3 are independently selected from linear, branched, and cyclic hydrocarbon groups having a total of from one to about eight carbon atoms, except that where one of R1, R2 or R3 is a phenyl group, the total of carbon atoms must be at least nine. They may be made by silylating the corresponding hydroxyl compound. They are useful as comonomers for olefins to introduce functional sites and may be copolymerized in Ziegler-Natta catalyst systems.

Dérivés silyliques d'eugénol comprenant des compositions de la formule (I), dans laquelle R1, R2 et R3 sont choisis indépendamment dans des groupes d'hydrocarbures linéaires, ramifiés et cycliques ayant un total de un à environ huit atomes de carbone exceptés ceux dans lesquels R1, R2 ou R3 représentent un groupe phényle, le total d'atomes de carbone devant être d'au moins neuf. Ils peuvent être obtenus par silylation du composé hydroxyle correspondant. Ils sont utiles en tant que comonomères pour des oléfines afin d'introduire des sites fonctionnels, et ils peuvent être copolymérisés dans des système catalytiques Ziegler-Natta.

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