Process for the enzymatic acylation of alcohols with...

Details Process for the enzymatic acylation of alcohols with... Process for the enzymatic acylation of alcohols with...

C - Chemistry, Metallurgy

12

P

C12P 7/62 (2006.01) C12P 41/00 (2006.01)

Patent

CA 2169683

The invention relates to a process for the enzymatic acylation of primary and secondary alcohols with enol esters, in particular alkoxyvinyl acetates, in organic media, in which the enol ester is cleaved into a single ester which is formed after enolization and an acyl radical; the latter is transferred to the alcohol in the solution, the transfer proceding enantioselectively in racemic or prochiral alcohols, i.e. selective acylation only of the one enantiomer or pro-enantiomer takes place, leaving behind the free alcohol of the other enantiomer or pro-enantiomer. The chiral acylated compounds and unreacted chiral alcohols can be separated from one another in a simple manner. The corresponding free alcohols can, if desired, be obtained from the acylated alcohols by simple ester cleavage.

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