Process for the preparation of a nickel/phosphorus ligand...

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B01J 37/16 (2006.01) B01J 31/16 (2006.01) B01J 31/18 (2006.01) B01J 31/30 (2006.01) C01G 53/09 (2006.01) C07C 253/10 (2006.01) C07F 15/04 (2006.01)

Patent

CA 2468293

A process for preparing a hydrocyanation catalyst comprising contacting a bidentate phosphorous-containing ligand with a nickel chloride in the presence of a nitrile solvent and a reducing metal which is more electropositive than nickel. Preferably, the nickel chloride is dried before use.

La présente invention concerne un procédé permettant de préparer un catalyseur d'hydrocyanation, qui consiste à mettre en contact un ligand bidenté à teneur en phosphore avec un excès molaire de chlorure de nickel en présence d'un solvant nitrile et d'un métal réducteur présentant une électropositivité supérieure à celle du nickel. De préférence, le chlorure de nickel est séché avant d'être utilisé.

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