Resins and compositions for the manufacture of high modulus...

C - Chemistry – Metallurgy – 08 – G

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C08G 18/67 (2006.01) C08G 18/46 (2006.01) C08G 18/50 (2006.01) C08G 18/63 (2006.01) C08G 18/68 (2006.01) C08L 75/06 (2006.01)

Patent

CA 2139219

Composite material produced from a first polyisocyanate-based mixture, from a second mixture comprising at least one ethylenically unsaturated monomer, at least one polyoxyalkylene polyamine and one ethylenically unsaturated polymer, and from a cross-linking catalyst. The first mixture comprises at least one polyisocyanate and at least one catalyst for reacting isocyanate functions with the ethylenically unsaturated polymer of the second mixture, and the second mixture comprises, for 100 parts by weight: 25 to 50 parts by weight of at least one ethylenically unsaturated monomer, 50 to 75 parts by weight of an unsaturated amine polyester resin which is the product of the reaction between (a) an unsaturated polyol polyester prepolymer and (b) a polyoxyalkylene amine, the weight ratio (a)/(b) being at least equal to 0.8, and as much as 4 parts by weight of at least one cross-linking catalyst. Application in the production of high modulus heat-resistant moulded articles.

Matériau composite obtenu à partir d'un premier mélange à base de polyisocyanate, d'un second mélange comprenant au moins un monomère éthyléniquement insaturé, au moins une polyamine polyoxyalkylène et un polymère éthylèniquement insatu- ré, et d'un catalyseur de réticulation. Le premier mélange comprend au moins un polyisocyanate et au moins un catalyseur de réaction des fonctions isocyanates avec le polymère éthylèniquement insaturé du second mélange, et le second mélange com- prend, pour 100 parties en poids: de 25 à 50 parties en poids d'au moins un monomère éthylèniquement insaturé, de 50 à 75 par- ties en poids d'une résine polyester insaturée aminée qui est le produit de la réaction entre (a) un prépolymère polyester polyol insaturé et (b) une amine polyoxyalkylène, le rapport en poids (a)/(b) étant au moins égal à 0,8 et jusqu'à 4 parties en poids d'au moins un catalyseur de réticulation. Application à l'obtention d'articles moulés de haut module et résistants à la chaleur.

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