Process for preparing .alpha.-d-glucopyranosido-1,6-mannitol...

C - Chemistry – Metallurgy – 07 – H

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C07H 15/04 (2006.01) C07H 15/08 (2006.01)

Patent

CA 2214623

The sugar alcohols mentioned as title compounds can be prepared from the corresponding sugar in equimolar amounts by catalytic hydrogenation with hydrogen in aqueous solution, the hydrogenation being carried out continuously at an H2 pressure of 100 to 400 bar and a reaction temperature of 20 to 80°C using fixed-bed support-free molded bodies composed of compacted powders of alloys of the elements of the iron subgroup of group VIIIA of the periodic table with elements of group IVB and VA. The molded bodies have a compressive strength of 20 to 220 N and an internal surface area of 10 to 95 m2/g.

Les alcools de sucres mentionnés peuvent être préparés en quantités équimolaires à partir du sucre correspondant, par hydrogénation catalytique avec l'hydrogène en solution aqueuse; l'hydrogénation est effectuée en continu à une pression H2 de 100 à 400 bars et à une température de réaction de 20 à 80 degrés C, à l'aide de corps moulés sans support et en lit fixe, constitués de poudres compactées d'alliages d'éléments du sous-groupe du fer du groupe VIIIA du tableau périodique avec des éléments des groupes IVB et VA. Les corps moulés ont une résistance à la compression de 20 à 220 N et une aire surfacique interne de 10 à 95 m2/g.

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