Vinylidene dimer process

C - Chemistry – Metallurgy – 07 – C

Patent

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260/707

C07C 2/30 (2006.01) C07C 11/02 (2006.01)

Patent

CA 2015068

Vinyl-olefins are converted to vinylidene olefin dimers at a selectivity of at least 85 mole percent by reacting a mixture of dry vinyl-olefin containing 0.001-0.04 moles of trialkyl aluminum per mole of initial vinyl-olefin at a temperature in the range of 100-140°C for a time sufficient to convert at least 80 mole percent of the initial vinyl-olefin to a different material.

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