Process for the manufacture of aliphatic alpha, omega amino...

C - Chemistry – Metallurgy – 07 – C

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C07C 253/30 (2006.01) C07C 209/48 (2006.01) C07C 211/12 (2006.01) C07C 255/24 (2006.01)

Patent

CA 2265513

Process for the manufacture of aliphatic alpha, omega amino nitriles by partial hydrogenation of aliphatic alpha, omega dinitriles in the presence of a catalyst, characterized by the fact that a catalyst is used for partial hydrogenation containing (a) iron or a compound based on iron or its mixtures and (b) 0.01 - 5 wt % related to (a) of a promotor on the basis of 2,3,4 or 5 elements selected from aluminium, silicon, zirconium, titanium and vanadium and (c) 0 - 5 wt % related to (a) of a compound based on an alkali metal or alkaline earth metal.

L'invention concerne un procédé pour la préparation d'alpha-oméga-aminonitriles aliphatique par hydrogénation partielle d'alpha, oméga-dinitriles aliphatiques en présence d'un catalyseur, caractérisé en ce que l'on utilise pour l'hydrogénation partielle un catalyseur qui contient, a) du fer ou un composé à base de fer ou leurs mélanges et b) de 0,01 à 5 % en poids par rapport à a), d'un promoteur à base de 2, 3, 4 ou 5 éléments choisis dans le groupe constitué de l'aluminium, silicium, zirconium, titane et du vanadium, ainsi c) de 0 à 5 % en poids par rapport a), d'un composé à base d'un métal alcalin ou alcalino-terreux.

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