Process for the production of olefins by autothermal cracking

C - Chemistry – Metallurgy – 10 – G

Patent

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Details

C10G 11/20 (2006.01) B01J 23/40 (2006.01) B01J 35/04 (2006.01) C07C 5/48 (2006.01) C10G 27/04 (2006.01)

Patent

CA 2593850

The present invention provides a process for the production of olefins by autothermal cracking of a paraffinic hydrocarbon-containing feedstock in the presence of a molecular oxygen-containing gas, wherein said process comprises (a) providing a pre-heated, mixed feedstream comprising said paraffinic hydrocarbon~containing feedstock and said molecular oxygen-containing gas, (b) subsequently mixing said pre-heated, mixed feedstream with a diluent, said diluent being pre-heated to a temperature of at least 400~C, to produce a diluted mixed feedstream comprising at least 10% by volume of diluent, and (c) contacting said diluted mixed feedstream with a catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability, to provide a hydrocarbon product stream comprising olefins.

La présente invention concerne un procédé pour la production d'oléfines par craquage autothermique d'une charge d'alimentation contenant un hydrocarbure paraffinique en présence d'un gaz contenant de l'oxygène moléculaire, ledit procédé comprenant (a) la formation d'une charge d'alimentation mélangée préchauffée comprenant ladite charge d'alimentation contenant un hydrocarbure paraffinique et ledit gaz contenant de l'oxygène moléculaire, (b) le mélange à la suite de cela de ladite charge d'alimentation mélangée préchauffée avec un diluant, ledit diluant étant préchauffé à une température d'au moins 400°C, pour produire une charge d'alimentation mélangée diluée comprenant au moins 10 % en volume de diluant et (c) la mise en contact de ladite charge d'alimentation mélangée diluée avec un catalyseur capable de supporter la combustion au-delà de la limite normale supérieure d'inflammabilité (mélange trop riche en combustible), pour produire un flux de produit hydrocarboné comprenant des oléfines.

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