Method of removing entrained sulfuric acid from alkylate

C - Chemistry – Metallurgy – 07 – C

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Details

C07C 7/144 (2006.01) C07C 2/62 (2006.01) C07C 7/04 (2006.01)

Patent

CA 2501305

An improvement in the alkylation of olefins with isoalkanes in the presence of sulfuric acid wherein the sulfuric acid is removed from the product by a mechanical coalescer means prior to fractionation. No water wash or caustic treatment is required. Any sulfonates or sulfonic esters are removed by hydrodesulfurization or decomposition catalyst in a separate reactor or in either the deisobutanizer (DIB) or debutanizer (DB) column.

La présente invention se rapporte à une amélioration relative à l'alkylation d'oléfines avec des isoalcanes en présence d'acide sulfurique, qui consiste à éliminer, avant le fractionnement, l'acide sulfurique du produit au moyen d'un dispositif mécanique à matériau coalescent. Aucun lavage à l'eau ni traitement à la soude caustique n'est requis. Tous les sulfonates ou les esters sulfoniques présents sont éliminés soit par un catalyseur d'hydrodésulfuration ou de décomposition dans un réacteur séparé soit dans la colonne de déisobutaniseur (DIB) ou de débutaniseur (DB).

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