Process for the preparation of 2-pyridylsulfonylureas, and...

C - Chemistry – Metallurgy – 07 – D

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C07D 401/12 (2006.01) C07D 401/14 (2006.01) C07D 413/14 (2006.01) C07D 513/04 (2006.01) C07D 521/00 (2006.01)

Patent

CA 2065802

ABSTRACT OF THE DISCLOSURE: HOE 91/F 108 Process for the preparation of 2-pyridylsulfonylureas, and thiadiazolopyridines as intermediates in this process The process according to the invention for the prepara- tion of herbicidal pyridylsulfonylureas of the formula (I) Image (I) in which R1 to R5 and X are as defined in claim 1 com- prises the reaction of the zwitterion (II) with the amino heterocycle (III) Image Image (II) (III) The novel zwitterionic 1,1,3-trioxo-1,2,4-thiadiazolo- [4,5-a]pyridines can be obtained according to the invention by the reaction of phosgene with compounds IV, or the reaction of phosgene with compounds V (IV) Image Image (V) in the presence of an alkyl isocyanate.

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