Perfluoroalky substituted anhydrides and polyacids, process...

C - Chemistry – Metallurgy – 07 – D

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403/14, 117/183,

C07D 307/89 (2006.01) C07D 307/93 (2006.01) C07D 493/04 (2006.01) C08G 18/10 (2006.01) C08G 18/50 (2006.01) C08K 5/09 (2006.01) C08K 5/12 (2006.01) C08K 5/16 (2006.01) C08K 5/37 (2006.01) C08K 5/372 (2006.01) C09D 5/02 (2006.01) D06M 13/213 (2006.01)

Patent

CA 1083164

Abstract of the Disclosure This invention relates to new perfluoroalkyl substituted esters, diesters and polyesters which contain at least one cyclic 5-membered anhydride group or two carboxy groups, as well as half amides and half esters thereof; further to the synthesis of these compounds and to their use as surface-active reactants in polycondensate resin systems. The anhydrides are synthesized by reaction of perfluoroalkyl substituted alcohols or diols with di- anhydrides or an anhydride-acid chloride and correspond to the general formula Image wherein Q is the tetra-radical rest of a tri- or tetra- carboxylic acid, which contains at least one 1,2-dicarboxy grouping, X is hydrogen or COOH, Rf is a perfluoroalkyl or perfluoroalkoxy- perfluoroalkyl group of 4 to 18 carbon atoms, a is 1 or 2, A is hydrogen or the group of the formula Image wherein m is an integer from 0 to 5, and R3 is the residue of a Rf substituted alcohol containing olefinic double bonds or oxygen, sulfur and/or nitrogen atoms or R3 is the residue of a Rf substituted diol.

269021

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