Process for the selective hydroformylation of methanol to...

C - Chemistry – Metallurgy – 07 – C

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260/572.1

C07C 47/06 (2006.01) C07C 45/49 (2006.01)

Patent

CA 1155458

12653 PROCESS FOR THE SELECTIVE HYDROFORMYLATION OF METHANOL TO ACETALDEHYDE ABSTRACT OF THE DISCLOSURE A process for the production of acetaldehyde from the cobalt-catalyzed, iodide-promoted reaction of methanol, hydrogen and carbon monoxide, attaining (a) selectivity to acetaldehyde heretofore unachievable and (b) high methanol conversion, wherein the reaction is carried out in an inert solvent at a temperature of from 100°C to 180°C with an iodide to cobalt mole ratio of from 2:1 to 100:1. S P E C I F I C A T I O N

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