Thermal shock resistant ceramic insulator

C - Chemistry – Metallurgy – 04 – B

Patent

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C04B 35/71 (2006.01) B22F 9/02 (2006.01) B22F 9/30 (2006.01) C22C 1/05 (2006.01) C22C 29/00 (2006.01) H01B 3/00 (2006.01) H01B 3/12 (2006.01)

Patent

CA 1131432

THERMAL SHOCK RESISTANT CERAMIC INSULATOR ABSTRACT Thermal shock resistant cermet insulators containing 0.1-20 volume % metal present as a dispersed phase. The insulators are prepared by a process com- prising the steps of (a) providing a first solid phase mixture of a ceramic powder and a metal precursor; (b) heating the first solid phase mixture above the minimum decomposition temperature of the metal precursor for no longer than 30 minutes and to a temperature sufficiently above the decomposition temperature to cause the selective decomposition of the metal precursor to the metal to provide a second solid phase mixture comprising particles of ceramic having discrete metal particles adhering to their surfaces, said metal particles having a mean diameter no more than 1/2 the mean diameter of the ceramic particles, and (c) densifying the second solid phase mixture to provide a cermet insulator having 0.1-20 volume % metal present as a dispersed phase.

341373

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