Process for the production of tertiary alcohols

Details Process for the production of tertiary alcohols Process for the production of tertiary alcohols

C - Chemistry, Metallurgy

07

C

260/639.4

C07C 31/12 (2006.01)

Patent

CA 1133523

ABSTRACT Tertiary alcohols are produced by the hydration of an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinyl- benzene copolymer and in the presence of a neo-type poly- hydric alcohol such as neopentyl glycol or an oxy acid or lactone thereof such as .gamma.-valerolactone. The process is useful for separating isobutylene from a hydrocarbon mix- ture containing its isomers via preparation of the alcohol, separation from the unreacted hydrocarbons and dehydration of the tertiary butyl alcohol to isobutylene.

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