Process for producing 2,3,5-trichloropyridine,...

C - Chemistry – Metallurgy – 07 – D

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260/295.2, 260/5

C07D 213/61 (2006.01) C07C 121/34 (1980.01)

Patent

CA 1123836

Abstract A novel process for producing 2,3,5-trichloropyridine is described. The process comprises the addition reaction of trichloroacetaldehyde with acrylonitrile in the presence of a catalyst, and the subsequent cyclisation of the intermediately formed 2,4,4-trichloro-4-formylbutyronitrile, with the splitting-off of water, to give 2,3,5-trichloro- pyridine. 2,4,4-Trichloro-4-formylbutyronitrile occurring as an intermediate product in the process according to the invention is a novel compound. It can be produced by the addition reaction of trichloroacetaldehyde with acrylo- nitrile in the presence of a catalyst. 2,3,5-Trichloropyridine can be used as intermediate for the production of herbicidal active substances.

341061

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