Process for alkylating aromatic hydrocarbons and catalyst...

Details Process for alkylating aromatic hydrocarbons and catalyst... Process for alkylating aromatic hydrocarbons and catalyst...

B - Operations, Transporting

01

J

252/1, 260/684

B01J 29/00 (2006.01) C07C 2/00 (2006.01)

Patent

CA 1071609

ABSTRACT OF THE DISCLOSURE Alkylatable aromatic hydrocarbons are alkylated with olefins and alkylhalides under anhydrous alkylating conditions in the presence of a metallic cation exchanged trioctahedral 2:1 layer-lattice smectit- type catalyst in which the metallic cation has a Pauling electronegativity greater than 1Ø In a specific embodiment, 1-dodecene is reacted with benzene by contacting the dodecene and benzene under anhydrous conditions in the liquid phase at the boiling point of the mixture with a catalyst comprising a metallic cation such as A13+, In3+ and Cr3+ exchanged onto the surface of hectorite clay.

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