Production of acetamides with rhodium-manganese catalysts

Details Production of acetamides with rhodium-manganese catalysts Production of acetamides with rhodium-manganese catalysts

C - Chemistry, Metallurgy

07

C

260/557.2

C07C 231/00 (2006.01)

Patent

CA 1142546

12,069 PRODUCTION OF ACETAMIDES WITH RHODIUM- MANGANESE CATALYSTS ABSTRACT OF THE DISCLOSURE A heterogeneous process for selectively producing acetamides in which the acyl nitrogen is otherwise bonded to methyl, ethyl, hydrogen or combinations thereof which comprises contacting a mixture of carbon monoxide, hydrogen and a nitrogen-containing compound selected from the group consisting of ammonia, nitric oxite and mixtures thereof with a heterogeneous solid catalyst comprising rhodium and manganese. The acetamides of the invention are formed in a collective amount of at least 25 weight percent of the total amide products of the reaction. SPECIFICATION - 1 -

366395

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