Process for isolating and recovering meta- and para-cresols...

C - Chemistry – Metallurgy – 07 – C

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202/63

C07C 37/78 (2006.01) C07C 39/07 (2006.01)

Patent

CA 1152933

Abstract of the Disclosure: A improvement in the process for isolating and recovering meta- and para-cresols from crude cresom- containing compositions composed of cresol components, unreacted cymene components and high-boiling by-products, by distillation in a distillation zone, the characteristic features residing in that; (i) the unreacted cymene components content in the crude cresol-containing composition is adjusted to 5-25% by weight of said composition after the adjustment and the water content of said composition is adjusted to become 0.17-1.5 times by weight of the total cresol- components present in the composition, before the crude cresol-containing composition is supplied to the distilla- tion zone, and also in that (ii) in said distillation zone, the cresol com- ponent containing ortho-cresol at a higher concentration than that in the supplied crude cresol-containing composi- tion is distilled off as an azeotropic mixture with the unreacted cymene components and water, whereby the cresol component composed of more condensed meta- and para-cresols being isolated and recovered.

355616

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