Coal gasification process

C - Chemistry – Metallurgy – 10 – G

Patent

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48/35, 48/46, 48

C10G 3/00 (2006.01) C10J 3/20 (2006.01) C10J 3/46 (2006.01) C10J 3/54 (2006.01) C10J 3/64 (2006.01) C10K 1/00 (2006.01)

Patent

CA 1133256

ABSTRACT OF THE DISCLOSURE A process for gasifying coal and other carbon- aceous matter is disclosed which produces fuel gas con- taining low concentrations of polycyclic aromatic hydro- carbons. In this process the polycyclic aromatic hydro- carbons released by the coal during devolatilization and formed during pyrolysis of volatile matter are decomposed thermally in the presence of hydrogen, at a sufficiently high partial pressure (obtained by increasing the total pressure in the gasifier) to prevent polymerization of free radicals formed during pyrolysis. A relationship between the temperature, the gas residence tine in the gasification reactor, the hydrogen partial pressure (i.e., total pressure in the gasifier), and the coal feed condi- tions are specified to achieve "clean" coal gasification

374788

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