Photochemical separation of isotopes

Details Photochemical separation of isotopes Photochemical separation of isotopes

B - Operations, Transporting

01

D

204/91.8

B01D 59/38 (2006.01) B01D 59/34 (2006.01)

Patent

CA 1122567

TITLE PHOTOCHEMICAL SEPARATION OF ISOTOPES INVENTOR Andreas Ch. Vikis Abstract of the Disclosure A method for photochemical separation or enrichment of isotopes of carbon-13 and oxygen-18 employing 123.58 nm resonance radiation of Kr of selected band-width and degrees of self-absorption in order to excite selectively to the AlII v' = 13 state, 13C16O, 12C18O, or both 13C16O and 12C18O simultaneously,in a mixture of isotopic CO molecules where the 12C16O isotopic molecule is in a large excess. The electronically excited isotopic CO molecules react with a second reactant to yield isotope enriched final products which can be separated; for example, ground state CO as second reactant yields CO2 and C3O2 products.

343201

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