Polymerisation process

C - Chemistry – Metallurgy – 08 – F

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402/373, 402/381

C08F 2/14 (2006.01) C08F 2/24 (2006.01) C08F 10/02 (2006.01) C08F 110/02 (2006.01) C08F 210/16 (2006.01)

Patent

CA 1046696

ABSTRACT OF THE DISCLOSURE Process for the dispersion polymerisation or co- polymerisation of olefins, especially ethylene alone or with an .alpha.-olefine, which is conducted in the presence of a surface- active compound containing one or more perfluorocarbon groups and, optionally, one or more hydrophilic groups, to reduce fouling of the reactor with adherent polymer particles. Particularly effective when olefins are polymerised with supported transition metal hydrocarbyl catalysts in non-polar hydrocarbon diluents.

217899

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