Metallocene intercalates

Details Metallocene intercalates Metallocene intercalates

C - Chemistry, Metallurgy

07

F

260/426

C07F 11/00 (2006.01) C07F 15/00 (2006.01) C07F 17/00 (2006.01)

Patent

CA 1055956

ABSTRACT OF THE DISCLOSURE A new group of materials is afforded by the intercalation of metal- locenes into the layered structure of metal dichalcogenides, said new material being represented by the general formula: TZ2 M(C5Hm-qXq)2 n where T is a member of Group IVb, Vb, tin, or mixtures thereof, or is a mixture of Group Vb and VIb wherein Vb is at least 50% of the mixture, Z is sulfur, selenium, or mixtures thereof, M is chromium, cobalt, iridium, rhodium or mixtures thereof, n is 0.10 to 0.4, m is 5, q is 0 to 5 and X is an organic radical which is the same or different and is selected from the group consisting of C1-C12 linear and branched hydro- carbyls, C3-C12 cyclic alkyls, C2-C12 alkenyls, C2-C12 alkynyls, C1-C12 alkoxy, C6-C18 aryloxy, C6-C18 aryls.

238997

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