Process for the carbonylation of alkanols and/or ethers

C - Chemistry – Metallurgy – 07 – C

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260/495.1

C07C 69/14 (2006.01) C07C 69/24 (2006.01)

Patent

CA 1156259

A B S T R A C T A PROCESS FOR THE CARBONYLATION OF ALKANOLS AND/OR ETHERS Process for the carbonylation of alkanols and/or ethers at elevated temperature and pressure in the presence of a Group VIII metal compound and pentachlorobenzenethiol and/or salts thereof, using a pentachlorobenzenethiol compound : Group VIII metal compound molar ratio of not more than 10. The process is of special interest for the production of methyl acetate from methanol using an active, iodine-free catalytic system.

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