Plasticized thermoplastic block and graft copolymers

C - Chemistry – Metallurgy – 08 – L

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400/3070

C08L 53/00 (2006.01) C08K 5/00 (2006.01) C08K 5/01 (2006.01) C08L 25/16 (2006.01) C08L 51/06 (2006.01) C08L 9/00 (2006.01)

Patent

CA 1047191

ABSTRACT OF THE DISCLOSURE Plasticized thermoplastic copolymer composition are dis- closed wherein the copolymer is selected from the group consisting of block copolymers having the general formulae (I) A-B-A, (II) A-B-A-B-A and (III) xB[A-B]n-yA and graft copolymers having the general formula (IV) Image , wherein m and n are integers greater than or equal to 2; x and y are 0 or 1, and y is 0 when n is 2; and A and B are mutually incompatible thermoplastic vinyl aromatic polymers blocks selected from the group of poly(alkyl styrene), poly(.alpha.-methyl stryene) and poly(alkyl.alpha.-methyl styrene) having a solubility parameter difference of greater than 0.7, each block having a molecular weight of at least 5000, a glass transition temperature of at least 35°C and provided the end block B segments in formula (III) do not exceed 35% by weight of the total amount of B segments present in the copolymer; and the plasticizer is selected from the group consisting of plasticizers having a solubility parameter within 1.2 units of the solubility parameter of said B polymer block, and the solubility parameter of said plasticizer is closer to the solubility parameter of said b block than said A block. These plasticized phase separated block copolymers have a combination of good strength and elastomeric behavior, not found in the prior art plasticized copolymers.

207791

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