Process for the preparation of water dispersible polyurethanes

C - Chemistry – Metallurgy – 08 – G

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402/131, 400/741

C08G 18/38 (2006.01) C08G 18/08 (2006.01) C08G 18/50 (2006.01) C08L 75/08 (2006.01)

Patent

CA 1061043

Abstract of the Disclosure This invention relates to a process for the production of water dispersible polyurethanes by reacting polyisocyanates with sulphonate group containing diols. The sulphonate diol- have the general formula: Image wherein A and B, which may be the same or different, each represents a divalent aliphatic hydro- carbon group containing from 1 to 6 carbon atoms, R represents hydrogen an aliphatic hydro- carbon group containing 1 to 4 carbon atoms or a phenyl group, x(+) represents an alkali metal carbon or ammonium group which may be substitured n and m, which may be the same or different, each represents an integer between 0 and 30 inclusive, o and p, represent 0 or 1, and q represents an integer of 0 or 2 sufficient amounts of this diol are used to provide the final poymer with a suphonate group content of about 0.1 LeA 15,933 to 6 wt.%. In a preferred embodiment, a prepolymer is formed in substance with the sulphonate bearing diol, the polyiso- cyanate and optionally other reactive hydrogen bearing com- pounds. The prepolymer is then chain extended with water and water soluble polyamines. This second stage may take place in water and the polyamines may carry sulphonate groups.

235512

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