Process for the preparation of polymers of alpha-olefins

C - Chemistry – Metallurgy – 08 – F

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402/638, 252/97

C08F 4/68 (2006.01) C08F 2/06 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1119154

ABSTRACT A solution polymerization process for the preparation of homopolymers of ethylene and copolymers of ethylene and higher .alpha.-olefins and a coordination catalyst for such a process are disclosed. In the process monomer is polymerized in the presence of the coordination catalyst which consists of a particular admixture of (a) a solution of an organoaluminum compound and an organomagnesium compound, with (b) a solution of a titanium compound and a vanadium compound. The catalyst exhibits relatively high activity in the polymerization of the monomers.

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