Preparation of pesticidal benzyl esters

C - Chemistry – Metallurgy – 07 – C

Patent

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260/479.1, 260/4

C07C 69/00 (2006.01) A01N 29/00 (2006.01) A01N 31/04 (2006.01) A01N 37/34 (2006.01) A01N 53/00 (2006.01) B01J 31/02 (2006.01) C07B 61/00 (2006.01) C07C 41/00 (2006.01) C07C 43/00 (2006.01) C07C 47/54 (2006.01) C07C 69/02 (2006.01) C07C 69/76 (2006.01) C07C 253/00 (2006.01) C07C 255/38 (2006.01) C07C 69/74 (2006.01)

Patent

CA 1122224

A B S T R A C T Process for the preparation of an ester of the general formula:- Image II wherein R is an optionally substituted alkyl or cycloalkyl group and A is phenoxy, phenylthio or benzyl, which comprises reacting a benzaldehyde of the formula:- Image III with an acyl halide of the formula R.CO.Hal (wherein Hal is bromide or chloride) in the presence of water, a water-soluble cyanide, a substantially water-immiscible aprotic solvent and a phase transfer catalyst.

271451

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