[1,2,4]-dithiazoli(di)ne derivatives, inducers of...

C - Chemistry – Metallurgy – 07 – D

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C07D 285/01 (2006.01) A61K 31/425 (2006.01) A61K 31/427 (2006.01) A61P 25/28 (2006.01) C07D 401/12 (2006.01) C07D 403/12 (2006.01)

Patent

CA 2597523

The present invention relates to 5-imino-5H-[1,2,4]-dithiazol-3-yl-amine and [1,2,4]- dithiazolidine-3,5-diylidene-diamine derivatives as inducers of glutha-thione-S- transferase (GST) and NADPH quinone oxidoreductase (NQO), to methods for the preparation of these compounds and to novel intermediates useful for the synthesis of said [1,2,4]-dithiazoli(di)ne derivatives. The invention also relates to the use of a compound disclosed herein for the manufacture of a medicament useful in the for prophylaxis and treatment of adverse conditions associated with cytotoxicity in general and apoptosis in particular. The invention relates to compounds of the general formula (I): wherein the symbols have the meanings given in the specification.

L'invention concerne des dérivés de 5-imino-5H-[1,2,4]-dithiazol-3-yl-amine et de [1,2,4]- dithiazolidine-3,5-diylidène-diamine utilisés comme inducteurs de la glutha-thione-S- transférase (GST) et de la NADPH quinone oxydoréductase (NQO), des procédés de préparation de ces composés et des intermédiaires utiles pour la synthèse des dérivés de [1,2,4]-dithiazoli(di)ne. L'invention concerne également l'utilisation d'un composés selon l'invention pour la fabrication d'un médicament utile dans la prophylaxie et le traitement d'états nocifs associés à la cytotoxicité en général et, plus particulièrement, à l'apoptose. L'invention concerne enfin des composés de formule générale (I) dans laquelle les symboles ont les significations données dans la description.

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