1 .alpha.-fluoroacrylic acid esters and polymers thereof

Details 1 .alpha.-fluoroacrylic acid esters and polymers thereof 1 .alpha.-fluoroacrylic acid esters and polymers thereof

C - Chemistry, Metallurgy

07

C

402/511, 260/481

C07C 69/653 (2006.01) C07C 51/34 (2006.01) C07C 51/377 (2006.01) C07C 51/60 (2006.01) C08F 20/22 (2006.01)

Patent

CA 1280118

Abstract of the disclosure: .alpha.-Fluoroacrylic acid esters and polymers thereof Esters of .alpha.-fluoroacrylic acid are accessible by hydro- lysis of an .alpha.-hydroxymethyl-.alpha.-fluoromalonic acid ester, decarboxylation and dehydration of the hydrolysis product and subsequent esterification of the resulting .alpha.-fluoro- acrylic acid with an alcohol. The esters are polymeriz- able and are suitable for use as a starting material for preparing fluoropolymers which in turn are usable as materials for manufacturing transparent articles. The polymers are high-molecular and non-crystalline and have softening temperatures of above 100°C.

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