2,9-dioxa tricyclo [4,3,1,0.sup.3.sup.,.sup.7] decane...

Details 2,9-dioxa tricyclo [4,3,1,0.sup.3.sup.,.sup.7] decane... 2,9-dioxa tricyclo [4,3,1,0.sup.3.sup.,.sup.7] decane...

C - Chemistry, Metallurgy

07

D

260/353.1

C07D 493/18 (2006.01) C07D 311/94 (2006.01) C07D 493/08 (2006.01)

Patent

CA 1167459

ABSTRACT OF THE DISCLOSURE Novel and highly effective sleep inducing 3.beta.-hydroxy methyl-4.alpha.- hydroxy-8.beta.-alkoxy-2,9-dioxa tricyclo [4,3,1,03,7] decane compounds of the following Formula: Image in which R1 indicates an alkoxy group and preferably a lower alkoxy group, such as the methoxy group, the ethoxy group, or the n- butoxy group, while R2 indicates the 10-methylene group or the 10.alpha.-methyl group, are produced from didrovaltratum, i.e., 1-isovaleroxy-4- isovaleroxy methyl-7-acetoxy-spiro-oxirano-1,9-dihydrocyclo- patenta(c)pyrane or from extracts of plants of the genus Valeri- anaceae which contain about 70% of didrovaltratum. The novel compounds have a surprisingly low toxicity.

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