2-hydroxy methylcyclopro pylidenemethyl purines and...

C - Chemistry – Metallurgy – 07 – D

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Details

C07D 473/16 (2006.01) A61K 31/52 (2006.01) A61K 31/522 (2006.01) C07D 239/46 (2006.01) C07D 473/00 (2006.01) C07D 473/18 (2006.01)

Patent

CA 2366624

Compounds which are active against viruses have Formulas (1, 2, 3 and 4) wherein B is a purine or pyrimidine heterocyclic ring and is preferably selected from the group consisting of 6-aminopurine (adenine), 2,6-diaminopurine, 2-amino-6-azidopurine, 2-amino-6-cyclopropylaminopurine, 6-hydroxypurine (hypoxanthine), 2-amino-6- halo substituted purines, 2-amino-6-alkoxy substituted purines, 2-amino-6-hydroxypurine (guanine), 3-deaza-purines, 7-deaza-purines, 8-azapurines, cytosine, 5-halo substituted cytosines, 5-alkyl substituted cytosines, thymine, uracil and 6-azapyrimidines; X is O; and, R1 and R2 are alkyl or aryl groups. The compounds of the present invention also include the R- and S-enantiomers of the above compounds. The R1X and/or R2X can also be amino acid residues with X as NH.

L'invention concerne des composés actifs contre des virus, représentés par les formules 1, 2, 3 et 4, dans lesquelles B est un noyau hétérocyclique purine ou pyrimidine, et est de préférence sélectionné dans le groupe constitué par 6-aminopurine (adénine), 2,6-diaminopurine, 2-amino-6-azidopurine, 2-amino-6-cyclopropylaminopurine, 6-hydroxypurine (hypoxanthine), des purines 2-amino-6-halo substituées, des purines 2-amino-6-alcoxy substituées, 2-amino-6-hydroxypurine (guanine), des 3-déazapurines, des 7-déaza-purines, des 8-azapurines, la cytosine, des cytosines 5-halo substituées, des cytosines 5-alkyle substituées, la thymine, l'uracile et des 6-azapyrimidines; X représente O; et R1 et R2 sont des groupes alkyle ou aryle. Les composés de la présente invention comprennent également les énantiomères -R et -S des composés cités précédemment. R1X et/ou R2X peuvent également être des résidus d'acides aminés, X représentant NH.

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