3-acylamino-3-deoxyallose derivatives

Details 3-acylamino-3-deoxyallose derivatives 3-acylamino-3-deoxyallose derivatives

C - Chemistry, Metallurgy

07

H

260/230.58

C07H 5/06 (2006.01) C07H 9/04 (2006.01) C07H 13/04 (2006.01)

Patent

CA 1285936

ABSTRACT OF THE DISCLOSURE Derivatives of 3-acylamino-3-deoxyallose represented by the following formula: Image wherein R1, R2, R3 and R4 may be hydrogen atoms, or R1 and R2, and R3 and R4 may be in combination an isopropylidene group, R5 represents a hydrogen atom or alkyl group, and R6 represents a hydrogen atom or acyl group, are disclosed. One of the typical compound 3-deoxy-3-(3-tetradecanoyloxytetra- decanoylamino)-1,2:5,6-di-O-isopropylidene-.alpha.-D-allofuranose is prepared by reacting 3-tetradecanoyloxytetradecanoic acid and 3-amino-3-deoxy-1,2:5,6-di-O-isopropylidene-.alpha.-D- allofuranose in the presence of N,N'-dicyclohexylcarbodiimide, as a dehydrating agent. The compound has an excellent carcinostatic activity.

563041

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