3-hydroxy-2-cyclobuten-1-one salts, their production and use

C - Chemistry – Metallurgy – 07 – C

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260/583.9

C07C 49/707 (2006.01) C07C 45/43 (2006.01) C07C 45/51 (2006.01) C07C 45/63 (2006.01) C07C 45/64 (2006.01) C07C 45/67 (2006.01) C07C 45/68 (2006.01) C07C 49/573 (2006.01) C07C 211/05 (2006.01) C07C 211/35 (2006.01)

Patent

CA 2036808

Novel 3-hydroxy-2-cyclobuten-1-one salts are disclosed of the general formula: (see formula I) wherein R is an alkali metal atom or an ammonium group of the general formula: (see fig II) wherein R1, R2 and R3 are the same or different in meaning and each is a hydrogen atom, a lower alkyl group or a cycloalkyl group. The salts of formula I are obtained by the reaction of 3-acetoxy-2-cyclobuten-1-one, 1,3-cyclobutanedione or a distillation residue of diketene production containing 3-acetoxy-2-cyclobuten-1-one, with a base. The base can be an amine of the general formula: Image wherein R1, R2 and R3 have the above-mentioned meaning, or an alkali metal alcoholate or an alkali metal hydroxide. The salts of formula I are suitable for the production of squaric acid, by halogenation in a first step and then hydrolysis to form squaric acid in a second step.

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