A blowing agent containing catalyst precursor for the...

C - Chemistry – Metallurgy – 08 – J

Patent

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Details

C08J 9/08 (2006.01) C08G 18/18 (2006.01) C08G 18/28 (2006.01)

Patent

CA 2212145

Disclosed is a blowing agent containing catalyst precursor consisting essentially of: a) a blowing agent comprising formic acid, or a mixture of formic acid and water; b) a tertiary amine blowing catalyst fully blocked with an organic carboxylic acid; and c) a tertiary amine gel catalyst fully blocked by an organic carboxylic acid; wherein the total number of carboxylic acid group equivalent including the carboxylic acid groups blocking in the Image form, is greater than 1.0 per amino group. This precursor can be used for the preparation of a polyol composition having good flow characteristics which in turn makes a rigid polyurethane having good dimensional stability at low densities.

On divulgue un agent gonflant contenant un précurseur de catalyseur constitué essentiellement : a) d'un agent gonflant comprenant de l'acide formique ou un mélange d'acide formique et d'eau; b) d'un catalyseur de gonflement à base d'amine tertiaire entièrement bloquée par un acide carboxylique organique; et c) d'un gel catalyseur à base d'amine tertiaire entièrement bloquée par un acide carboxylique organique; où le nombre total de groupes carboxyliques équivalents, incluant les groupes carboxyliques bloquants dans la forme Image , est supérieur à 1,0 par groupe aminé. Ce précurseur peut être utilisé pour la préparation d'une composition polyolique dotée de bonnes caractéristiques d'écoulement qui permettent d'obtenir un polyuréthane rigide ayant une bonne stabilité dimensionnelle à faible densité.

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