A gas phase polymerization employing unsupported catalysts

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 2/34 (2006.01) C08F 10/00 (2006.01) C08F 36/00 (2006.01) C08F 4/619 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2186302

A process for the gas-phase polymerization of polymers which allows for the introduction of an unsupported polymerization catalyst system into the gas-phase reactor, wherein the unsupported polymerization catalyst system comprises (i) a non-volatile materials fraction containing a polymerization catalyst; (ii) a solvent fraction which is at least partially miscible with the non-volatile materials fraction and which is sufficiently volatile to allow for the formation of polymerization catalyst particles when the mixture of the solvent fraction and the non-volatile materials fraction is sprayed into the reactor; (iii) a compressed fluid; and (iv) optionally a slowly vaporizing solvent.

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