A method for the demercaptanization of petroleum distillates

C - Chemistry – Metallurgy – 10 – G

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C10G 27/04 (2006.01) B01J 21/18 (2006.01) B01J 23/70 (2006.01) B01J 31/28 (2006.01) B01J 35/06 (2006.01) C10G 27/10 (2006.01)

Patent

CA 2199373

The demercaptanization of petroleum distillates may be carried out by means of the oxidation of the mercaptans contained therein using the oxygen in the air, at a temperature of about 80 to about 220 ~C, in the presence of about 0.01 to about 10.0 mass % of a water-soluble salt of copper, iron, nickel, or cobalt, on a fibrous carbonaceous material in the form of a woven fabric, felt, rope, or twisted strand, used as a heterogeneous catalyst. The fibrous carbonaceous material used in the process contains oxides of calcium, magnesium, copper, manganese, iron, zinc, and aluminum in an amount of up to about 0.03 mass %.

La démercaptanisation de produits de la distillation du pétrole peut être réalisée par oxydation des mercaptans contenus dans ces produits à l'aide de l'oxygène de l'air, à une température comprise entre environ 80~ et environ 220 ~C, en présence d'environ 0,01 à environ 10 % du volume d'un sel de cuivre, fer, nickel ou cobalt soluble dans l'eau, sur un matériau carboné fibreux se présentant sous la forme d'un tissu non tissé, feutre, corde ou cordon toronné, utilisé comme catalyseur hétérogène. Le matériau carboné fibreux utilisé dans le procédé contient des oxydes de calcium, magnésium, cuivre, manganèse, fer, zinc et aluminium dans une quantité représentant jusqu'à environ 0,03 % du volume.

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