A method for the targeted execution of a reaction taking...

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 45/29 (2006.01) C07C 49/603 (2006.01)

Patent

CA 2657059

A method for the targeted execution of a reaction taking place alongside several competing chemical reactions is described, wherein the speeds of the competing reactions are set by the selection of the reaction conditions in such a way that the desired main reaction is not adversely affected. The invention further describes a new method for the oxidation of primary or secondary alcohols into aldehydes or ketones in the presence of dimethyl sulfoxide, a carboxylic acid anhydride or halogenide, and an amine in an organic solvent, in a continuous processing system (Moffatt-Swern oxidation).

L'invention concerne un procédé pour la réalisation ciblée d'une réaction en présence de plusieurs réactions chimiques concurrentes. Selon ce procédé, les vitesses des réactions concurrentes sont ajustées par le choix des conditions de réaction, de sorte que la réaction principale souhaitée ne soit pas influencée de manière défavorable. L'invention concerne en outre un nouveau procédé d'oxydation d'alcools primaires ou secondaires en aldéhydes ou cétones, en présence de diméthylsulfoxyde, d'un anhydride ou halogénure d'acide carboxylique et d'une amine, dans un solvant organique dans une installation de processus continu (oxydation de Moffat-Swern).

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