A process for selectively hydrogenating butadiene in an c4...

C - Chemistry – Metallurgy – 07 – C

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C07C 5/05 (2006.01) C07C 5/25 (2006.01) C07C 11/08 (2006.01)

Patent

CA 2650930

A process for selectively hydrogenating butadiene that is contained in a C4 stream having a concentration of a catalyst poison and C4 olefins, including 1-butene, and further the process provides for the substantial isomerization of the 1-butene to 2-butene of the C4 olefin stream, wherein the process comprises contacting, under suitable process conditions, the C4 stream with a poison tolerant catalyst comprising an alumina support material and partially sulfided nickel on the alumina support material at a concentration in the range of from 5 to 40 weight percent nickel, and yielding a product having a minimal butadiene concentration and a reduced concentration 1-butene.

L'invention concerne un procédé d'hydrogénation sélective de butadiène qui est contenu dans un flux C4 présentant une concentration d'un poison de catalyseur et d'oléfines C4, notamment de butène-1. L'invention concerne également le procédé d'isomérisation sensible du butène-1 en butène-2 du flux d'oléfines C4, le procédé consistant à mettre en contact, dans des conditions de traitement appropriées, le flux C4 présentant un catalyseur tolérant au poison comprenant un matériau support d'alumine et du nickel partiellement sulfuré sur le matériau support d'alumine selon une concentration comprise entre 5 et 40 % en poids de nickel, et à obtenir un produit présentant une concentration en butadiène minimale et une concentration en butène-1 réduite.

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